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Question-211819




Question Number 211819 by Spillover last updated on 22/Sep/24
Answered by TonyCWX08 last updated on 22/Sep/24
i.  Benzene can be prepared from Phenol through reduction.  Vapour of Phenol passes over heated Zinc Dust.  Zinc Dust will reduces them into Benzene    ii.  Benzene can be prepared from Benzenesulphonic acid through hydrolysis.  Benzenesulphonic Acid is exposed to superheated steam leading to the formation of Benzene.    iii.  Benzene can be prepared from Ethyne through process of cyclic polymerization.  Ethyne is passed through a red−hot iron at 873K.  Ethyne Molecules then undergoes cyclic polymerization to form Benzene    iv.Two ways:  a. Sodium benzoate is heated with a mixture of Sodium Hydroxide and Calcium Oxide to form Benzene.  b. Sodium benzoate is heated with Anhydrous Ferric Chloride to form Benzene.    v.   Firstly, Oxidize Toluene with Hot Potassium Manganate solution and then react with Sodium Hydroxide or Calcium Oxide.
$${i}. \\ $$$${Benzene}\:{can}\:{be}\:{prepared}\:{from}\:{Phenol}\:{through}\:{reduction}. \\ $$$${Vapour}\:{of}\:{Phenol}\:{passes}\:{over}\:{heated}\:{Zinc}\:{Dust}. \\ $$$${Zinc}\:{Dust}\:{will}\:{reduces}\:{them}\:{into}\:{Benzene} \\ $$$$ \\ $$$${ii}. \\ $$$${Benzene}\:{can}\:{be}\:{prepared}\:{from}\:{Benzenesulphonic}\:{acid}\:{through}\:{hydrolysis}. \\ $$$${Benzenesulphonic}\:{Acid}\:{is}\:{exposed}\:{to}\:{superheated}\:{steam}\:{leading}\:{to}\:{the}\:{formation}\:{of}\:{Benzene}. \\ $$$$ \\ $$$${iii}. \\ $$$${Benzene}\:{can}\:{be}\:{prepared}\:{from}\:{Ethyne}\:{through}\:{process}\:{of}\:{cyclic}\:{polymerization}. \\ $$$${Ethyne}\:{is}\:{passed}\:{through}\:{a}\:{red}−{hot}\:{iron}\:{at}\:\mathrm{873}{K}. \\ $$$${Ethyne}\:{Molecules}\:{then}\:{undergoes}\:{cyclic}\:{polymerization}\:{to}\:{form}\:{Benzene} \\ $$$$ \\ $$$${iv}.{Two}\:{ways}: \\ $$$${a}.\:{Sodium}\:{benzoate}\:{is}\:{heated}\:{with}\:{a}\:{mixture}\:{of}\:{Sodium}\:{Hydroxide}\:{and}\:{Calcium}\:{Oxide}\:{to}\:{form}\:{Benzene}. \\ $$$${b}.\:{Sodium}\:{benzoate}\:{is}\:{heated}\:{with}\:{Anhydrous}\:{Ferric}\:{Chloride}\:{to}\:{form}\:{Benzene}. \\ $$$$ \\ $$$${v}.\: \\ $$$${Firstly},\:{Oxidize}\:{Toluene}\:{with}\:{Hot}\:{Potassium}\:{Manganate}\:{solution}\:{and}\:{then}\:{react}\:{with}\:{Sodium}\:{Hydroxide}\:{or}\:{Calcium}\:{Oxide}. \\ $$
Commented by Spillover last updated on 22/Sep/24
correct
$${correct} \\ $$
Answered by Spillover last updated on 22/Sep/24

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