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Question Number 211845 by Spillover last updated on 22/Sep/24

Answered by Spillover last updated on 22/Sep/24

  The order of increasing election donating power is  +R> +hyperconjugation> +Inductive   Methoxy has +mesmeric effect, which highly increases the election density at the carbon connected to the NH2 gp .So the lone pair over N is maximum available for coordination to H+.So this compound is maximum basic.The second position for p - toluidine.The methyl group donates election density by hyperconjugation and+I effects.Aniline comes third.Nitro gp in meta position shows mainly--I effect.In para position,Nitro group shows _R effect with extended conjugation involving nitro group.So para nitro aniline is least basic

The order of increasing election donating power is +R> +hyperconjugation> +Inductive Methoxy has +mesmeric effect, which highly increases the election density at the carbon connected to the NH2 gp .So the lone pair over N is maximum available for coordination to H+.So this compound is maximum basic.The second position for p - toluidine.The methyl group donates election density by hyperconjugation and+I effects.Aniline comes third.Nitro gp in meta position shows mainly--I effect.In para position,Nitro group shows _R effect with extended conjugation involving nitro group.So para nitro aniline is least basic

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